
Iron-based wrought high-temperature alloys yog ib chav kawm ntawm cov khoom siv hlau nrog hlau (Fe) ua lub hauv paus tseem ceeb, tsim kom muaj lub zog zoo thiab ua haujlwm tsis zoo (xws li oxidation) ntawm qhov kub siab, feem ntau nyob rau hauv thaj tsam ntawm 540 ° C txog 760 ° C (1000 ° F txog 1400 ° F). Lub npe "wrought" qhia tias lawv tau zoo li tus txheej txheem thermomechanical xws li kub dov, forging, los yog extrusion, uas ua kom zoo dua lawv cov microstructure los muab kev sib xyaw ua ke ntawm lub zog, ductility, thiab fabricability.
Lawv ua hauj lwm raws li tus nqi-zoo thiab muaj ntau yam kev daws teeb meem rau ntau qhov sib txawv ntawm cov kev siv kub-kub, bridging qhov kev sib txawv ntawm cov hlau tsis muaj steel thiab kim nickel lossis cobalt-based superalloys.
Zoo Siab Kub Lub Zog & Creep Resistance: Lawv tiv taus deformation thiab qeeb, lub sij hawm-dependent strain (ceep) nyob rau hauv mechanical load ntawm qhov kub siab, txawm tias lawv lub siab kub txwv feem ntau qis dua cov nickel-based superalloys.
Zoo heev Oxidation & Corrosion Resistance: Ib qho tseem ceeb feature yog lawv lub peev xwm los tsim ib tug tiv thaiv, adherent chromia (Cr₂O₃) nplai rau saum npoo, ua tsaug rau cov ntsiab lus chromium siab (feem ntau 12-28%). Ntau qib kuj tseem muaj silicon (Si) thiab txhuas (Al) los tsim cov nplai ntau dua.
Nqi-Kev Ua Tau Zoo: Raws li cov hlau matrix, lawv tsis tshua kim dua li cov nickel lossis cobalt-raws li kev xaiv, ua rau lawv cov khoom xaiv rau cov ntawv loj lossis cov nqi-rhiab heev.
Zoo Fabricability: Lawv qhov wrought xwm txhais tau tias lawv tuaj yeem ua tau yooj yim tsim, machined, thiab welded rau hauv cov khoom siv uas siv cov qauv kev lag luam.
Kev ua haujlwm siab kub ntawm cov hlau no tau ua tiav los ntawm ntau qhov kev sib koom ua ke:
Kev Siv Lub Zog Muaj Zog: Cov ntsiab lus zoo li molybdenum (Mo), tungsten (W), thiab chromium (Cr) yaj hauv cov hlau matrix, cuam tshuam kev txav mus los thiab muab lub zog hauv paus.
Carbide Precipitation Strengthening: The formation of stable carbides (e.g., M₂₃C₆, MC, where M is Cr, Mo, Nb) at grain boundaries and within the grains helps to pin dislocations and grain boundaries, enhancing strength and creep resistance.
Nitride thiab Carbonitride Precipitation: Hauv qee cov alloys, cov ntsiab lus xws li niobium (Nb) thiab titanium (Ti) tsim cov nitrides lossis carbonitrides uas muab cov dej nag ntxiv.
Microstructural Stability: Cov khoom sib xyaw alloy yog sib npaug los tiv thaiv cov coarsening ntawm cov theem ntxiv dag zog thiab tsim kom muaj kev puas tsuaj intermetallic compounds thaum lub sij hawm ntev raug tshav kub.
Hlau-raws li wrought high-temperature alloys yog workhorses nyob rau hauv ntau industries:
Kev tsim hluav taws xob:
Turbine Blades & Discs nyob rau hauv chav turbines thiab qis-kub theem ntawm roj turbines.
Boiler Tubing, Superheater & Reheater Tubes, thiab cov khoom siv hluav taws xob sib hloov hauv cov roj hluav taws xob fossil.
Automotive:
Turbocharger Housings (Turbine Housings) uas yuav tsum tiv taus cov pa cua kub.
Exhaust Manifolds thiab downpipes.
Industrial Furnaces & Kev kho cua sov:
Radiant Tubes, Muffles, Tais, thiab pob tawb siv hauv carburizing, annealing, thiab lwm yam txheej txheem kho cua sov.
Petrochemical thiab Refining:
Tubing rau cov cua sov coils thiab cov kav dej rau cov txheej txheem kub kub hauv cov catalytic crackers thiab hloov kho.
Cov lus hauv qab no qhia txog cov yam ntxwv tseem ceeb rau kev saib xyuas sai:
| Feature | Kev piav qhia | Qhov zoo |
| Base Element | Hlau (Fe), nrog siab Chromium (Cr) cov ntsiab lus. | Muab tus nqi tsim nyog nrog lub hauv paus oxidation tsis kam. |
| Txoj kev tsim khoom | Thermomechanical Processing (Kub Rolling, Forging). | Ua rau ib tug uniform, nplua-grained qauv nrog zoo ductility thiab toughness. |
| Key Strengtheners | Kev daws teeb meem (Mo, W); Carbides (Cr, Nb, Mo). | Muab qhov sib npaug sib npaug ntawm qhov kub thiab txias zog thiab microstructural stability. |
| Qhov kub thiab txias | Kev ua tau zoo txog ~ 760 ° C (1400 ° F). | Sau qhov sib txawv tseem ceeb ntawm kev ua haujlwm ntawm tus qauv stainless hlau thiab nickel superalloys. |
| Cov txiaj ntsig tseem ceeb | Qhov zoo tshaj plaws sib npaug ntawm kev ua tau zoo, fabricability, thiab nqi. | Qhov kev daws teeb meem zoo tshaj plaws rau ntau qhov kev sib tw kub-kub engineering. |
| Common Alloys & Hom | Austenitic (piv txwv li, 304H, 316H, 321H, 347H); Ferritic (piv txwv li, 446); Los nag-Hardenable (piv txwv li, A-286, 17-4PH). | Muaj ntau txoj kev xaiv rau qhov sib txawv ntawm qhov kub thiab txias, lub zog, thiab corrosion. |
Hauv cov ntsiab lus, Hlau-raws li Wrought High-temperature Alloys yog cov chav kawm tseem ceeb thiab muaj ntau yam ntawm cov ntaub ntawv uas ua rau muaj feem ntau ntawm kev tsim hluav taws xob niaj hnub high-temperature. Lawv txoj kev loj hlob sawv cev rau kev ua kom zoo ntawm tus nqi thiab kev ua tau zoo, ua rau lawv tseem ceeb rau cov ntawv thov xws li tsev neeg lub tsheb mus rau cov chaw tsim hluav taws xob uas muab nws cov hluav taws xob.